英语高手来来

The past few decades have seen a significant growth in the field of supramolecular
polymerizations,in which(reversible)noncovalent interactions(e.g.,hydrogen bonding,metal-ligand
coordination,π-πstacking,etc.)between(macro)monomeric units are utilized to build polymeric assem-
blies.These polymeric aggregates can exist in an equilibrium state between low and high molecular weight
species,which in turn opens the door to a new matrix of properties.For example,such supramolecular
polymers are potentially an interesting class of stimuli-or environmentally responsive,“smart”materials.
Additionally,the establishment of an equilibrium during the assembly process imparts on the system the
ability to“proofread”assemblies and,depending on the nature of the(macro)molecules,can allow efficient
access to controlled,well-defined nanostructures.This Perspective will focus on the basic concepts of
such supramolecular polymerizations,such as mechanism of assembly growth,and the effects of growth
kinetics,phase segregation,and growth on the surface has on the assembly and properties of the resulting
supramolecular polymers,highlighting these concepts with selected literature examples.

过去几十年来，在外地的显着增长超分子

聚合反应，其中（可逆）非共价键相互作用（如氢键，金属配体

协调，π-πstacking等之间的（宏观）单体单元）则用于建立聚合物获益良多，

blies.These聚合物聚集体可以存在于高，低之间的分子量平衡状态

物种，从而开启了大门，例如新的properties.For矩阵，如超分子

聚合物可能刺激有趣的一个阶级或环境反应，“智能”材料。

此外，在系统上的装配过程传授建立一个平衡

能够“校对”集会，并根据对（宏观性质）分子，可以让效率

访问控制，明确界定nanostructures.This观点将侧重于基本概念

这种超分子聚合反应，如集会增长机制和增长的影响

动力学，相塞格雷

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